• Title of article

    Preparation of ethylene-bridged Group 14 metal–zirconocene complexes

  • Author/Authors

    Yasuyuki Ura، نويسنده , , Ryuichiro Hara، نويسنده , , Tamotsu Takahashi، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    299
  • To page
    303
  • Abstract
    The reactions of the zirconocene–ethylene complex Cp2Zr(CH2CH2)(PMe3) with Group 14 metal chlorides or alkoxides give ethylene-bridged group 14 metal–zirconocene complexes. A reaction mechanism via a five-membered intermediate which involves direct coupling of ethylene and single bonding is proposed.
  • Keywords
    Ethylene-bridged , Silyl , Germanium , zirconocene , Ethylene complexes , TIN , ?-coupling
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1371274