Title of article :
Preparation of ethylene-bridged Group 14 metal–zirconocene complexes
Author/Authors :
Yasuyuki Ura، نويسنده , , Ryuichiro Hara، نويسنده , , Tamotsu Takahashi، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
The reactions of the zirconocene–ethylene complex Cp2Zr(CH2CH2)(PMe3) with Group 14 metal chlorides or alkoxides give ethylene-bridged group 14 metal–zirconocene complexes. A reaction mechanism via a five-membered intermediate which involves direct coupling of ethylene and single bonding is proposed.
Keywords :
Ethylene-bridged , Silyl , Germanium , zirconocene , Ethylene complexes , TIN , ?-coupling
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry