Title of article
Selective hydrosilylation of allyl esters with octahydridosilsesquioxane
Author/Authors
Masayasu Igarashi، نويسنده , , Toshiaki Kobayashi، نويسنده , , Kazuhiko Sato، نويسنده , , Wataru Ando، نويسنده , , Tomohiro Matsumoto، نويسنده , , Shigeru Shimada، نويسنده , , Masanao Hara، نويسنده , , Hiroshi Uchida، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2013
Pages
6
From page
54
To page
59
Abstract
Hydrosilylation of allyl esters with octahydridosilsesquioxane (T8H8) in the presence of platinum-based catalysts was studied. The effects of the catalysts and the reaction conditions on the conversion and the selectivity of the products were investigated. Karstedtʹs catalyst with two equivalents of PPh3 was found to be a superior hydrosilylation catalyst in terms of conversion and selectivity, compared with other Pt catalysts examined. An octasilsesquioxane functionalized with epoxy substituents was synthesized using the optimized reaction system, which was converted to a thermosetting polymer and its properties were investigated.
Keywords
Octasilsesquioxanes , allyl esters , Catalysis , Thermosetting resins , Hydrosilylation
Journal title
Journal of Organometallic Chemistry
Serial Year
2013
Journal title
Journal of Organometallic Chemistry
Record number
1371361
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