Title of article :
B-frame supported bimetallics. ‘Composite cluster’ compounds and the structures of [2,7-(η5-C5Me5)2-nido-2,7,8,6-Ir2CSB6H8] and its 9-chloro derivative. Synchrotron and conventional X-ray studies
Author/Authors :
PAUL K. COOKE، نويسنده , , Caroline OʹDowd، نويسنده , , Michael G.S. Londesborough، نويسنده , , Josef Holub، نويسنده , , Bohumil ?t??br، نويسنده , , Mark Thornton-Pett، نويسنده , , William Clegg، نويسنده , , Simon J Teat، نويسنده , , John D Kennedy، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
Reaction of [IrCl2(η5-C5Me5)]2 with the [hypho-CSB6H11]− anion gives [2,7-(η5-C5Me5)2-nido-2,7,8,6-Ir2CSB6H8] and [2,7-(η5-C5Me5)2-nido-2,7,8,6-Ir2CSB6H7-9-Cl] which exhibit composite cluster features in which the {IrSIrC} string and the {B6} unit occupy separate domains within the overall contiguous nido-type ten-vertex {Ir2SCB6} cluster unit.
Keywords :
Borane cluster , Thiaborane cluster , Composite cluster , B-frame bimetallics , X-ray , Synchrotron , NMR , Metallacarbathiaborane , Carbathiaborane cluster
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
