Title of article
Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)2N][(HRu4(CO)12BH)2Ag]
Author/Authors
Catherine E. Housecroft، نويسنده , , Sylvia M. Draper، نويسنده , , Andrew T. Hattersley، نويسنده , , Arnold L Rheingold، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
6
From page
202
To page
207
Abstract
Reaction of [(Ph3P)2N][HRu4(CO)12BH] with [Cu(NCMe)4][BF4] in the presence of [(Ph3P)2N]Cl leads to [(Ph3P)2N][(HRu4(CO)12B)2Cu4(μ-Cl)]Cl, confirmed by a single crystal structure determination. A silver analogue is produced from the reactions of [(Ph3P)2N][HRu4(CO)12BH] with [Ag(NCMe)4][BF4] or AgBF4, but its formation competes with that of [(Ph3P)2N][(HRu4(CO)12BH)2Ag], the crystal structure of which has been determined.
Keywords
Ruthenium , Silver , copper , Cluster fusion , Boron
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1371499
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