• Title of article

    (Diazomethyl)silyl-functionalized Fischer-type carbene complexes

  • Author/Authors

    Gerhard Maas، نويسنده , , Dieter Mayer، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    7
  • From page
    339
  • To page
    345
  • Abstract
    The synthesis of two types of so far unknown title compounds is described. Carbene complexes LnMC(R)OSiR2C(N2)COOMe [LnM(OC)5W (3), (OC)5Cr (4), (OC)5Mo (5), (MeCp)(OC)2Mn (6)] were obtained from the corresponding acyl metalates by electrophilic (diazomethyl)silylation. Similarly, (diazomethyl)silylation of lithiated dicarbonyl(η5-methylcyclopentadienyl)(1-ethoxyethylidene)manganese yielded a manganese carbene complex (8a) with CH2SiR2C(N2)COOMe substitution.
  • Keywords
    Fischer-type carbene complexes , diazo compounds , silyl triflates
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1371614

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1371614