مرکز منطقه ای اطلاع رساني علوم و فناوري - Synthesis and reactivity of subvalent compounds: Part 10. Fast deuterium labeling and the basicity of stable diamino carbenes (imidazole-2-ylidenes)

Title of article :

Synthesis and reactivity of subvalent compounds: Part 10. Fast deuterium labeling and the basicity of stable diamino carbenes (imidazole-2-ylidenes)

Author/Authors :

Michael K. Denk، نويسنده , , José M. Rodezno، نويسنده ,

Issue Information :

دوفصلنامه با شماره پیاپی سال 2001

Pages :

From page :

737

To page :

740

Abstract :

The aromatic ring protons in imidazol-2-ylidenes (Arduengo carbenes) undergo rapid deuterium–hydrogen exchange in DMSO-d6, CD3OD and D2O.

Keywords :

carbenes , Imidazol-2-ylidenes , Hydrogen–deuterium exchange , Proton affinities , DFT calculations , mechanism

Journal title :

Journal of Organometallic Chemistry

Serial Year :

2001

Journal title :

Journal of Organometallic Chemistry

Record number :

1371685

Link To Document :