Title of article
Palladium complex-catalyzed germylation of allylic halides using (germyl)stannanes
Author/Authors
Taichi Nakano، نويسنده , , Kazuyoshi Ono، نويسنده , , Yoshiya Senda، نويسنده , , Toshihiko Migita، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
5
From page
313
To page
317
Abstract
(Triethylgermyl)tributylstannane reacts metal-selectively with allylic halides at room temperature (r.t.) in the presence of tris(dibenzylideneacetone)dipalladium, Pd2(dba)3CHCl3, to provide an alternative route to allylgermanes. (Dimethylphenylgermyl)tributylstannane regio- and stereoselectively reacts more readily with allylic halides than (triethylgermyl)tributylstannane affording the corresponding allylgermanes in quantitative yields.
Keywords
allyl halides , Germylstannanes , Palladium catalysis , Metathesis , Allylgermanes
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1371763
Link To Document