Title of article
Heck-type coupling of intramolecularly-generated thiopalladacycles with alkenes: One pot syntheses of 3-alkenylbenzo[b]thiophenes
Author/Authors
Manjusha V. Karkhelikar، نويسنده , , Shailesh S. Racharlawar، نويسنده , , Subhas M. Salian، نويسنده , , B. Sridhar، نويسنده , , Pravin R. Likhar، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2012
Pages
7
From page
128
To page
134
Abstract
A method for stoichiometric functionalization of benzothiophene is developed by Heck-type coupling of alkenes with intramolecularly-generated thiopalladacycles obtained from palladium salts and ortho-thioanisole-substituted propargyl imines. The synthetic strategy for preparing structurally diverse 3-alkenylbenzo[b]thiophene is also extended to 3-alkenylbenzo[b]selenophenes.
Keywords
Heck-type coupling , alkene , Thiopalladacycle , Palladium
Journal title
Journal of Organometallic Chemistry
Serial Year
2012
Journal title
Journal of Organometallic Chemistry
Record number
1372466
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