Title of article :
Bridging allyl ligands upon allene insertion into electron-deficient triosmium-hydride clusters [Os3(CO)9(μ3-NSC7H3R)(μ-H)] (R = H, Me)
Author/Authors :
Md. Iqbal Hossain، نويسنده , , Shishir Ghosh، نويسنده , , Graeme Hogarth، نويسنده , , G.M. Golzar Hossain، نويسنده , , Shariff E. Kabir، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
Allene reacts with the benzothiazolide clusters [Os3(CO)9(μ3-NSC7H3R)(μ-H)] (R = H, Me) to afford the bridging allyl complexes [Os3(CO)7(μ-CO)2(μ-NSC7H3R)(μ-η1:η2:η1-CH2CHCH2)] resulting from insertion of allene into the metal–hydride. Both have been crystallographically characterized and differ with respect to the relative arrangement of allyl and benzothiazolide at the triosmium centre.
Keywords :
Allene insertion , Bridging allyl ligand , Triosmium clusters , X-Ray structures , Carbonyls
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry