Title of article
Heck arylation of allylic alcohols in molten salts
Author/Authors
Sandrine Bouquillon، نويسنده , , Benjamin Ganchegui، نويسنده , , Boris Estrine، نويسنده , , Françoise Hénin، نويسنده , , Jacques Muzart، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
4
From page
153
To page
156
Abstract
The Heck coupling of ArX (X=I, Br) with allylic alcohols, carried out at 80–120 °C in molten n-Bu4NBr using NaHCO3 as base and PdCl2 as catalyst without extra ligands, leads to the corresponding β-arylated carbonyl compounds. After extraction of the organic materials with diethyl ether, the ionic layer can be reused directly.
Keywords
Heck reactions , allylic alcohols , Recycling , Molten ammonium salts
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1373225
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