Title of article
Ferrocene as a ferromagnetic coupler. Synthesis and characterization of a ferrocene bridged polychlorotriphenylmethyl diradical
Author/Authors
O Elsner، نويسنده , , D Ruiz-Molina، نويسنده , , Imma Ratera، نويسنده , , J Vidal-Gancedo، نويسنده , , C Rovira، نويسنده , , J Veciana، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
7
From page
251
To page
257
Abstract
A polychlorotriphenylmethyl diradical connected by a 1,1′-ferrocenylendivinylene bridge has been synthesized and characterized. ESR frozen solution experiments down to helium temperature showed that the organometallic unit acts as a ferromagnetic coupler. This fact was supported by ZINDO/1 semiempirical calculations, which showed that the two singly occupied molecular orbitals (SOMOs) are non disjoint in addition to be almost degenerated.
Keywords
Organic radical , Ferromagnetism , Ferrocene , ESR
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1373376
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