Title of article :
Ru(II)-Catalyzed rearrangement of 2-aryl-2-(phenylthio)penta-3,4-dienyl 2,2,2-trichloroacetimidates
Author/Authors :
Lingling Peng، نويسنده , , Xiu Zhang، نويسنده , , Jie Ma، نويسنده , , Jianbo Wang ، Yan Yan ، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
[RuCl2(p-cymene)]2 efficiently catalyzes the rearrangement of 2-aryl-2-(phenylthio)penta-3,4-dienyl 2,2,2-trichloroacetimidate to afford (Z)-2,2,2-trichloro-N-(4-aryl-1-(phenylthio)penta-2,4-dien-2-yl)acetamide. Ru carbene is assumed as the reactive intermediate in this rearrangement.
Keywords :
Ru(II) catalysis , 1 , Rh(II) carbene , 4-Thio shift , rearrangement , Allene
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
