Title of article
Copper(I)-catalyzed hydrophosphination of styrenes
Author/Authors
Antonio Leyva-Pérez، نويسنده , , Jose A. Vidal-Moya، نويسنده , , Jose R. Cabrero-Antonino، نويسنده , , Salem S. Al-Deyab، نويسنده , , Saud I. Al-Resayes، نويسنده , , Avelino Corma، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
6
From page
362
To page
367
Abstract
Hydrophosphination of styrenes has been accomplished with metal salts for the first time. (CuOTf)2·toluene complex is the catalyst of choice, but CuCl can also be used. “In-situ” EPR and NMR studies suggest Cu(I) as the catalytically active metal species, giving exclusively the anti-Markovnikov product. Phosphine oxides or β-ketophosphine oxides can be prepared in one-pot by oxidation with molecular oxygen.
Keywords
Styrenes , ?-Ketophosphines , phosphine oxides , hydrophosphination , Tertiary phosphines , Copper(I) catalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373534
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