Title of article
Palladium-catalyzed asymmetric allylic alkylations of cycloalkenyl acetates with planar chiral phosphino-ferrocene carboxylic acids
Author/Authors
Shu-Li You، نويسنده , , Yu-Mei Luo، نويسنده , , We-Ping Deng، نويسنده , , Xue-Long Hou، نويسنده , , Lixin Dai، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
5
From page
845
To page
849
Abstract
New phosphino-ferrocene carboxylic acids with only planar chirality (Sp)-3 and (Sp)-4 have been synthesized conveniently from (S,Sp)-5 and (S,Sp)-7. They were used as ligands in palladium-catalyzed allylic alkylation of cycloalkenyl acetates. With ligand (Sp)-4, high yield and good ee were given for reactions of a series of cycloalkenyl acetates and nucleophiles.
Keywords
Alkylation , Asymmetric catalysis , Ferrocene , planar chirality
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1373566
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