Title of article
Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation
Author/Authors
Claudia S. Straubinger، نويسنده , , Nade?da B. Joki?، نويسنده , , Manuel P. H?gerl، نويسنده , , Eberhardt Herdtweck، نويسنده , , Wolfgang A. Herrmann، نويسنده , , Fritz E. Kühn، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
6
From page
687
To page
692
Abstract
A series of chelating bridge functionalized bis-N-heterocyclic carbenes (NHC) complexes of rhodium (I) were prepared by reacting the corresponding imidazolium salts with [Rh(COD)Cl]2 in an in-situ reaction. For the N-methyl substituted complex with a PF6-anion an X-ray crystal structure was exemplary obtained. All complexes were spectroscopically characterized and tested for the hydrosilylation of acetophenone.
Keywords
Bridge functionalization , Hydrosilylation (hydrosilation) , Rhodium , N-heterocyclic carbene
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373607
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