Author/Authors :
Tatiana A. Kochina، نويسنده , , Dmitriy V. Vrazhnov، نويسنده , , Igor S. Ignatyev، نويسنده , , Eugenia N. Sinotova، نويسنده , , Mikhail G. Voronkov، نويسنده ,
Abstract :
Radiochemical studies of nucleogenic trivalent cations of the 14th group elements (silicon and germanium) generated by the β-decay of tritium atoms incorporated into organometallic molecules are reviewed. The radiochromatographic analysis of the neutral labeled products of reactions of these cations with various nucleophiles combined with quantum chemical data allowed us to obtain new information about the reactivity and rearrangements of silylium and germylium cations.
