Title of article
Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst
Author/Authors
Nobuyuki Komine، نويسنده , , Kohtaro Ishiguro، نويسنده , , Sachiyo Kanai، نويسنده , , Masafumi Hirano، نويسنده , , Sanshiro Komiya، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
4
From page
1927
To page
1930
Abstract
[RhCl(1,5-cod)]2/PTA is highly active branch-selective catalyst for C-allylation of acetylacetone by allylic carbonates in water/ethyl acetate biphasic system, where either crotyl or 1-methylallyl carbonates gives sterically congested branched allylation product, suggesting formation of a common allylrhodium intermediate.
Keywords
Water-soluble rhodium complex , Branch-selective allylation , Biphasic catalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373939
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