Title of article
Regioselective reactions of sulfur, selenium and tellurium chlorides with allyl trimethyl silane
Author/Authors
Alexander V. Martynov، نويسنده , , Natalia A. Makhaeva، نويسنده , , Lyudmila I. Larina، نويسنده , , Svetlana V. Amosova، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
5
From page
1964
To page
1968
Abstract
Electrophilic addition of SCl2, SeCl2 and SeCl4 to 2 equivalents of allyl trimethyl silane proceeds regioselectively to give bis[2-chloro-3-(trimethylsilyl)propyl] sulfide, selenide and selenium dichloride, respectively. The reaction with TeCl4 affords only diallyl tellurium dichloride. The structures of the compounds were confirmed by 1H, 13C, 77Se and 125Te NMR techniques.
Keywords
NMR spectroscopy , Allyl trimethyl silane , Selenium dichloride , Chalcogen chlorides , Diallyl tellurium dichloride , Regioselective electrophilic addition
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373947
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