Title of article
Observation of inter- and intramolecular CH⋯F hydrogen bonding in Gingrasʹ salt: [n-Bu4N]+[Ph3SnF2]−
Author/Authors
Jens Beckmann، نويسنده , , Dainis Dakternieks، نويسنده , , Andrew Duthie، نويسنده , , Edward R.T. Tiekink، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
5
From page
204
To page
208
Abstract
The crystal and molecular structure of Gingrasʹ salt [n-Bu4N]+ [Ph3SnF2]− is reported, which reveals a variety of inter- and intramolecular CH⋯F hydrogen bonding interactions. A 119Sn MAS-NMR spectrum was recorded and a tensor analysis has been performed according to the method of Herzfeld and Berger. The results are discussed in terms of the molecular structure and are compared with the parent compound Ph3SnF as well as with Mes3SnF (Mes=mesityl).
Keywords
hypercoordination , Organotin , Fluoride , 119Sn MAS-NMR , X-Ray structures
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374162
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