• Title of article

    Observation of inter- and intramolecular CH⋯F hydrogen bonding in Gingrasʹ salt: [n-Bu4N]+[Ph3SnF2]−

  • Author/Authors

    Jens Beckmann، نويسنده , , Dainis Dakternieks، نويسنده , , Andrew Duthie، نويسنده , , Edward R.T. Tiekink، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    204
  • To page
    208
  • Abstract
    The crystal and molecular structure of Gingrasʹ salt [n-Bu4N]+ [Ph3SnF2]− is reported, which reveals a variety of inter- and intramolecular CH⋯F hydrogen bonding interactions. A 119Sn MAS-NMR spectrum was recorded and a tensor analysis has been performed according to the method of Herzfeld and Berger. The results are discussed in terms of the molecular structure and are compared with the parent compound Ph3SnF as well as with Mes3SnF (Mes=mesityl).
  • Keywords
    hypercoordination , Organotin , Fluoride , 119Sn MAS-NMR , X-Ray structures
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374162