• Title of article

    Dicationic triple-decker complexes with a bridging boratabenzene ligand

  • Author/Authors

    Alexander R. Kudinov، نويسنده , , Dmitry A. Loginov، نويسنده , , Zoya A. Starikova، نويسنده , , Pavel V. Petrovskii، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    136
  • To page
    140
  • Abstract
    New dicationic triple-decker complexes with a bridging boratabenzene ligand [Cp*Fe(μ-η:η-C5H5BMe)ML]X2 (ML=CoCp*, 6(CF3SO3)2; RhCp, 7(BF4)2; IrCp, 8(CF3SO3)2; Ru(η-C6H6), 9(CF3SO3)2; Ru(η-C6H3Me3-1,3,5), 10(CF3SO3)2; Ru(η-C6Me6), 11(CF3SO3)2) were synthesized by stacking reactions of Cp*Fe(η-C5H5BMe) (2) with the corresponding half-sandwich fragments [ML]2+. The structure of 10(CF3SO3)2 was determined by X-ray diffraction study.
  • Keywords
    Boratabenzene , Triple-decker complexes , Sandwich compounds , Boron , X-ray structure , Cobalt , Ruthenium , Iron , Iridium , Rhodium
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374232