Title of article
Allylic boranes are chemist’s best friends: Reactivity, applications, new opportunities
Author/Authors
Yu.N. Bubnov، نويسنده , , M.E. Gurskii، نويسنده , , S.Yu. Erdyakov، نويسنده , , O.A. Kizas، نويسنده , , G.D. Kolomnikova، نويسنده , , A.Yu. Kuznetsov، نويسنده , , T.V. Potapova، نويسنده , , O.A. Varzatskii، نويسنده , , Y.Z. Voloshin، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
10
From page
1754
To page
1763
Abstract
Fruitful methods for the preparation of various (poly)unsaturated, (poly)cyclic and cage organic compounds with the use of allylic type organoboranes have been developed. Allylborane reactions proceeding with the rearrangement of allylic moiety or via a direct rupture of the B–C bond (with retention) little known to the boron community are considered. Synthesis of boron containing clathrochelates and some transformations of 1-boraadamantane, a unique cage compound, are also described.
Keywords
Allylboranes , allylboration , 1-Boraadamantanes , Clathrochelates , Osmium clusters
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374295
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