Title of article
Discovery of the cross-coupling reaction between Grignard reagents and C(sp2) halides catalyzed by nickel–phosphine complexes
Author/Authors
Kohei Tamao، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
4
From page
23
To page
26
Abstract
This mini-review traces the initial ideas, discoveries and significant features of the cross-coupling reaction between Grignard reagents and C(sp2)-halides such as aryl and alkenyl halides in the presence of a nickel–phosphine complex as a catalyst, which was first reported by Kohei Tamao, Koji Sumitani, and Makoto Kumada in 1972.
Keywords
Nickel–phosphine complex , Grignard reagent , Catalytic cycle , Oxidative addition , Reductive elimination , Transmetallation , cross-coupling reaction , aryl halide , Alkenyl halide
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374402
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