Title of article
Pyridylsilyl group-driven cross-coupling reactions
Author/Authors
Kenichiro Itami، نويسنده , , Koichi Mitsudo، نويسنده , , Toshiki Nokami، نويسنده , , Toshiyuki Kamei، نويسنده , , Tooru Koike، نويسنده , , Junichi Yoshida، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
9
From page
105
To page
113
Abstract
Summarized herein are the demonstrations that the use of 2-PyMe2Si group as a removable directing group is a powerful strategy for enhancing the efficiency of otherwise sluggish processes and for steering the course of the reaction by taking advantage of attractive substrate–catalyst interaction in the palladium-catalyzed cross-coupling chemistry. The 2-PyMe2Si group-driven Heck-type coupling, Hiyama-type coupling, Stille-type coupling, and allylic alkylation are described.
Keywords
Pyridylsilyl group , Removable directing group , cross-coupling reaction
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374421
Link To Document