Title of article :
1-Fluorosilatrane synthesis from SiF4 complexes and its properties
Author/Authors :
Sergey A. Lermontov، نويسنده , , Alena N. Malkova، نويسنده , , El’mira Kh. Lermontova، نويسنده , , Andrei V. Churakov، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2009
Abstract :
A new method of 1-fluorosilatrane synthesis on the basis of silicon tetrafluoride complexes obtained from SiO2 is offered. Chemical properties of 1-fluorosilatrane in reactions of nucleophilic substitution are investigated. It is shown that fluorine can be substituted by O-nucleophiles (lithium methoxide, isopropoxide and phenoxide) and C-nucleophile (lithium phenylacetylenide).
Keywords :
Silicon tetrafluoride , Silicon dioxide , 1-Fluorosilatrane
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry