Title of article
Coupling of ferrocenyl chromium carbene complex with cyclobutenediones
Author/Authors
Metin Zora، نويسنده , , Baris YUCEL، نويسنده , , N. Bekir Peynircioglu، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
7
From page
11
To page
17
Abstract
The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene-1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations.
Keywords
Cyclobutenedione , Coupling , Cyclopentenedione , Ferrocenyl carbene , Ferrocene , Fischer carbene , Alkylidenefuranone
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374591
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