Title of article
Polysubstituted derivatives of 3-(η5-Cp)-4-SMe2-3,1,2-FeC2B9H10. X-ray structure of 3-(η5-Cp)-4-SMe2-7,8-(CF3COO)2-12-HgCl-3,1,2-FeC2B9H7
Author/Authors
Vladimir I. Bregadze، نويسنده , , Irina A. Lobanova، نويسنده , , Sergey V. Timofeev، نويسنده , , Alexander R. Kudinov، نويسنده , , Vladimir I. Meshcheryakov، نويسنده , , Oleg L Tok، نويسنده , , Pavel V. Petrovskii، نويسنده , , Zoya A. Starikova، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
5
From page
171
To page
175
Abstract
The electrophilic mercuration of 3-(η5-Cp)-4-SMe2-3,1,2-FeC2B9H10 (1) was investigated. The reaction of 1 with the excess of mercury trifluoroacetate in dichloromethane at 20 °C gives complexes containing from two to four substituents depending on the ratio of reagents. All new compounds were separated and characterized by elemental analysis and NMR spectra. The positions of substitution were established by 11B-NMR and 11B-11B COSY NMR spectra. X-ray structure of 3-(η5-Cp)-4-SMe2-7,8-(CF3COO)2-12-HgCl-3,1,2-FeC2B9H7 was determined.
Keywords
Mercuration , X-ray diffraction , Ferracarboranes
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374711
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