Author/Authors :
Marc B. Taraban، نويسنده , , Alexander I. Kruppa، نويسنده , , Nikolai E. Polyakov، نويسنده , , Mikhail G. Voronkov، نويسنده , , Vladimir I. Rakhlin، نويسنده , , Stanislav V. Grigorʹev، نويسنده , , Olga S. Volkova، نويسنده , , Rudolph G. Mirskov، نويسنده , , Tatyana V. Leshina، نويسنده ,
Abstract :
Two instances have been considered demonstrating the influence of organoelement substituent on the reactivity of radicals generated from R3MCH2CHCH2 (M=Si or Sn) in photoinduced interaction with (Me3Si)2NBr. CIDNP studies has allowed to identify two different reaction mechanisms for M=Si or M=Sn which end up in two different sets of reaction products.
Keywords :
CIDNP , Homolytic substitution , Free radicals , ?-Cleavage , Radical pairs
