Title of article
Reaction of secondary phosphine selenides with the system Se/MOH (M = Li, Na, K, Rb, Cs): A novel three-component synthesis of diorganodiselenophosphinates
Author/Authors
Boris A. Trofimov، نويسنده , , Alexander V. Artem’ev، نويسنده , , Svetlana F. Malysheva، نويسنده , , Nina K. Gusarova، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
5
From page
4116
To page
4120
Abstract
Secondary phosphine selenides, R2P(Se)H (R = PhCH2CH2, PhCH(Me)CH2, 4-t-BuC6H4CH2CH2, NaphthylCH2CH2, Ph), react with the system Se/MOH (M = Li, Na, K, Rb, Cs) in the system THF/EtOH at ambient temperature unusually fast (20–30 s) to give cleanly and almost quantitatively (in 94–100% yield) earlier unknown diorganodiselenophosphinates of alkali metals.
Keywords
Secondary phosphine selenides , Elemental selenium , Alkali metal hydroxides , Diselenophosphinates
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374988
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