Title of article :
Cationic iridium–BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C–H bond cleavage
Author/Authors :
Kyoji Tsuchikama، نويسنده , , Mitsugu Kasagawa، نويسنده , , Yu-Ki Hashimoto، نويسنده , , Kohei Endo، نويسنده , , Takanori Shibata، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2008
Abstract :
Cationic Ir complex ([Ir(cod)2]BF4 + BINAP) catalyzed the addition of ortho-C–H bonds in aryl ketones to alkynes, which gave alkenylated products in good to high yield. Styrene derivatives were good substrates, and the enantioselective addition to norbornene was also described.
Keywords :
Iridium , C–H bond cleavage , Ketone , alkene , alkyne
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
