• Title of article

    Cross-coupling of (Z)-1,2-bis(ethylseleno)ethene with the Grignard reagents

  • Author/Authors

    Alexander V. Martynov، نويسنده , , Vladimir A. Potapov، نويسنده , , Svetlana V. Amosova، نويسنده , , Nataliya A. Makhaeva، نويسنده , , Irina P. Beletskaya، نويسنده , , Laszlo Hevesi، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2003
  • Pages
    3
  • From page
    101
  • To page
    103
  • Abstract
    The nickel-catalyzed cross-coupling of (Z)-1,2-bis(ethylseleno)ethene with the alkyl magnesium bromides proceeds with substitution of both ethylseleno groups to afford symmetrical alkenes, (Z)-RCHCHR, in high yield with complete retention of configuration. In the case of phenyl magnesium bromide the monoarylation occurs to form (Z)-2-ethylseleno styrene, EtSeCHCHPh.
  • Keywords
    1 , Cross-coupling , nickel , Selenide , cis-Alkenes , 2-Bis(ethylseleno)ethene
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2003
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1375686

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1375686