Title of article
Novel stereoselective synthesis of 1,3-dienylsilanes via hydromagnesiation reaction of alkynylsilanes
Author/Authors
Mingzhong Cai، نويسنده , , Wenyan Hao، نويسنده , , Hong Zhao، نويسنده , , Caisheng Song، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
3
From page
14
To page
16
Abstract
Hydromagnesiation of alkynylsilanes gives (Z)-α-silylvinyl Grignard reagents, which undergo palladium-catalyzed cross-coupling reactions with alkenyl halides to afford stereoselectively 1,3-dienylsilanes in good yields.
Keywords
cross-coupling reaction , Stereoselective synthesis , Alkynylsilane , Hydromagnesiation , 1 , 3-Dienylsilane
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375844
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