Title of article
The differences in solid state structures of C,N-chelated nbutyltin(IV) fluorides
Author/Authors
Petr ?vec، نويسنده , , Zde?ka Pad?lkov?، نويسنده , , Zden?k ?erno?ek، نويسنده , , Frank De Proft، نويسنده , , Ale? R??i?ka، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
5
From page
2937
To page
2941
Abstract
The solid state structures of products of fluorination of LCNnBuSnCl2 (where LCN is 2-[(CH3)2NCH2]C6H4–) by different methods are reported. The reaction of 3 equiv. of [NH4]+[LCNnBuSnF3]− and Pr(OTf)3 led to dimeric arrangement [LCNnBuSnF(μ-F)2SnLCNnBuF] · 2HOTf. Two different polymorphs of polymeric [LCNnBuSnF2]n have been obtained by crystallization. Prepared compounds were studied by X-ray crystallographic methods, DSC and theoretical calculations at the B3LYP/LANL2DZ level.
Keywords
Organotin(IV) fluorides , CN-ligand , structure
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376074
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