Title of article :
Thermal and photochemical reactions of Fischer carbene complexes with trialkylsilyl-substituted alkynes
Author/Authors :
Zhi Li ، نويسنده , , William H. Moser، نويسنده , , Wenqin Zhang، نويسنده , , Changhua Hua، نويسنده , , Liangdong Sun، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2008
Abstract :
Thermal reaction of Fischer carbene complexes with triisopropylsilyl (TIPS) substituted alkynes in benzene afforded TIPS-substituted vinylketenes or 2-TIPS-substituted cyclobutenones as major products while photochemical reaction of Fischer carbene complexes with trimethylsilyl (TMS) substituted alkynes in acetonitrile afforded 3-TMS-substituted cyclobutenones.
Keywords :
Fischer carbene , Cyclobutenone , Silyl vinylketene
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
