Title of article
Protonation of the lithio derivatives of the 1,2,4-tri-phosphaferrocenes, [LiFe(η4-P2C2tBu2PBu)(η5-C5R5)] (R = H, Me): Crystal and molecular structure of [Fe(η4-P3C2tBu2BuH)(η5-C5Me5)]
Author/Authors
Mahmoud M. Al-Ktaifani، نويسنده , , Peter B. Hitchcock، نويسنده , , John F. Nixon، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
4
From page
725
To page
728
Abstract
A new synthetic route is described to generate the 4-centre-5 electron donor ring system (P3C2tBu2BuH), via protonation of the lithium salts [LiFe(η4-P2C2tBu2PBu)(η5-C5R5)] (R = H, Me). The molecular structure of [Fe(η4-P3C2tBu2BuH)(η5-C5R5)] (R = Me) has been determined by a single crystal X-ray study.
Keywords
4-Centre-5 electron donor , Tri-phosphorus ring , Protonation , Lithium
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376354
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