Title of article
Novel fluoride ion mediated synthesis of unsymmetrical siloxanes under phase transfer catalysis conditions
Author/Authors
Ramona Abele، نويسنده , , Edgars Abele، نويسنده , , Mendel Fleisher، نويسنده , , Solveiga Grinberga، نويسنده , , Edmunds Lukevics، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
6
From page
52
To page
57
Abstract
Unsymmetrical siloxanes have been prepared from silanols or hydrosilanes using phase transfer catalytic (PTC) systems Me3SiN3–CsF–18-crown-6–toluene or Me3SiN3–CsF–18-crown-6–H2O–toluene, correspondingly. The target unsymmetrical siloxanes were prepared in yields up to 100%. Quantum chemical calculation of mechanism of unsymmetrical siloxanes formation has been performed.
Keywords
Fluoride ion , Unsymmetrical siloxanes , Phase transfer catalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376389
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