Title of article
trans-Bis-[(−)ephedrinate]-palladiumII complex: synthesis, molecular modeling and use as catalyst
Author/Authors
Sandrine Bouquillon، نويسنده , , Stéphane Humbel، نويسنده , , Ulla Létinois-Halbes، نويسنده , , Françoise Hénin، نويسنده , , Jacques Muzart، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
7
From page
377
To page
383
Abstract
The reaction between palladium acetate, (−)-ephedrine and potassium acetate led to bis-chelate complex Pd[OCH(Ph)NH(Me)]2 whose the trans-structure is obtained from calculations. The use of this complex to catalyze either the 1,4-hydrogenation of (E)-2-benzyliden-1-tetralone or Heck reaction of phenyl iodide with 3-methyl-3-buten-2-ol led to a low enantiomeric excess.
Keywords
Ephedrine , Chirality , palladium complexes , Pd?N bond , Density functional theory (DFT)
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376542
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