Title of article :
Convenient synthesis of Pt(0) olefin complexes by colorimetric reduction of Pt(II) complexes with SmI2
Author/Authors :
Sensuke Ogoshi، نويسنده , , Masaki Morita، نويسنده , , Katsuharu Inoue، نويسنده , , Hideo Kurosawa، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2004
Abstract :
Homoleptic olefin platinum(0) complexes, Pt(C7H10)3 and Pt(cod)2, were synthesized by the colorimetric reduction of platinum(II) complexes with SmI2 in the presence of 2-norbornene or COD. This is a practically more convenient method for the synthesis of the Pt(0) complexes than the literature method employing Li2(cot).
Keywords :
SmI2 , Colorimetric reduction , Homoleptic olefin platinum(0) complexes
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
