Title of article
Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation
Author/Authors
Guido D. Frey، نويسنده , , Rian D. Dewhurst، نويسنده , , Shazia Kousar، نويسنده , , Bruno Donnadieu، نويسنده , , Guy Bertrand، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
9
From page
1674
To page
1682
Abstract
A series of mono- and dicarbene gold(I) complexes of types Au(CAAC)(Cl) [CAAC = cyclic (alkyl)(amino)carbene] (1) and [Au(CAAC)2]+[X]− (X = Cl, AuCl2) (2) have been prepared through reaction of AuCl(SMe2) with free carbenes a–e, and structurally characterized by single X-ray diffraction studies (1a, 1b, 2d, 2e). In addition two new free cyclic (alkyl)(amino)carbenes (c and e) have been synthesized.
Keywords
Gold , Stable carbenes , carbene complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376884
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