Title of article
Synthesis and structure of an indium(I) “crown sandwich”
Author/Authors
Benjamin F.T. Cooper، نويسنده , , Charles L.B. Macdonald، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
5
From page
1707
To page
1711
Abstract
The treatment of the soluble reagent indium(I) trifluoromethanesulfonate, InOTf, with the crown ether 15-crown-5 generates the salt [In(15-crown-5)2][OTf] regardless of the stoichiometry employed. The toluene-soluble salt has been characterized by single-crystal X-ray diffraction and features a cation that may be described as containing an InI center that is “sandwiched” by the two crown ethers.
Keywords
Indium , Low oxidation state , Main group , Crown ether chemistry , Sandwich compounds
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376888
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