Author/Authors :
Sergey E. Lyubimov، نويسنده , , Andrey A. Tyutyunov، نويسنده , , Pavel A. Vologzhanin، نويسنده , , Anton S. Safronov، نويسنده , , Pavel V. Petrovskii، نويسنده , , Valery N. Kalinin، نويسنده , , Konstantin N. Gavrilov، نويسنده , , Vadim A. Davankov، نويسنده ,
Abstract :
A series of chiral diphosphite ligands bearing sterically congested carborane fragments have been prepared and applied in the Pd-catalyzed allylic amination of 1,3-diphenylallyl acetate with pyrrolidine and di-n-propylamine (up to 83% ee).
Keywords :
Phosphite ligands , Carboranes , Allylic amination , Palladium
