Title of article
η4-Phosphole tricarbonylmanganates: a new type of chelating ligands for transition metals
Author/Authors
Bernard Deschamps، نويسنده , , Louis Ricard، نويسنده , , François Mathey، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2004
Pages
3
From page
4647
To page
4649
Abstract
3,4-Dimethylphosphacymantrene (1) reacts with tert-butyllithium to give the corresponding (η4-3,4-dimethyl-1-tert-butylphosphole)tricarbonylmanganate (2) which can act as a chelating ligand (L) toward a Pd2Cl2 dimeric core. The X-ray crystal structure of L2Pd2Cl2 (3) shows a bite angle of 60.5°.
Keywords
Chelating ligands , Phosphate , Palladium , manganese
Journal title
Journal of Organometallic Chemistry
Serial Year
2004
Journal title
Journal of Organometallic Chemistry
Record number
1377516
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