Title of article
Epimerization, diastereoselectivity and hemilability in dicationic chiral ruthenium complexes with bidentate (P∧S) bisphosphine monosulfide ligands
Author/Authors
J.W Faller*، نويسنده , , Philip P. Fontaine، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
7
From page
976
To page
982
Abstract
The binding of heterobidentate P∧S ligands introduces metal-centered chirality to the planar chiral parent complex Ru(η6:η1-NMe2C6H4C6H4PCy2)Cl2. Observed diastereomeric ratios for the kinetic product vary dramatically depending upon ring size of the chelate formed with the P∧S ligand. The complexes epimerize very slowly to thermodynamic product ratios that are substantially different from the kinetic product ratios.
Keywords
Metal-centered chirality , Hemilabile , Chirality
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377587
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