Title of article :
New phosphorus dendrimers with chiral ferrocenyl phosphine-thioether ligands on the periphery for asymmetric catalysis
Author/Authors :
Lucie Routaboul، نويسنده , , Sandrine Vincendeau، نويسنده , , Cédric-Olivier Turrin، نويسنده , , Anne-Marie Caminade، نويسنده , , Jean-Pierre Majoral، نويسنده , , Jean-Claude Daran، نويسنده , , Eric Manoury، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
Chiral ferrocenyl phosphine-thioether ligands have been covalently bound on the periphery of 4 phosphorus dendrimers (generations 1–4) having a cyclotriphosphazene core and on one model compound. These new dendrimers proved to be efficient ligands for the palladium-catalyzed asymmetric allylic substitution reaction (ee up to 93%).
Keywords :
Ferrocenes , Phosphorus dendrimers , p , S ligands , Asymmetric catalysis
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
