Title of article :
Re-examination of the photochemical reaction of octaisopropylcyclotetragermane
Author/Authors :
Masanobu Wakasa، نويسنده , , Yuya Takamori، نويسنده , , Toshiyuki Takayanagi، نويسنده , , Masayuki Orihara، نويسنده , , Tsuyoshi Kugita، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
The photochemistry of octaisopropylcyclotetragermane was studied by laser flash photolysis and trapping experiments. Upon irradiation of the cyclotetragermane, the main reaction was a ring opening to form octaisopropyltetragermane-1,4-diyl biradical (λmax = 310 and 550 nm), but generations of diisopropylgermylene and tetraisopropyldigermene are negligible.
Keywords :
Cyclic oligogermanes , Germylene , Laser flash photolysis , Photochemistry , biradical
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
