Title of article
Sulfur-alkylation-initiated Cp∗Ru thiyl radicals
Author/Authors
Richard Yee Cheong Shin، نويسنده , , Hui Shan Sim، نويسنده , , Lai Yoong Goh، نويسنده , , Richard D. Webster، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
10
From page
3267
To page
3276
Abstract
The formation of thiyl radicals from [Cp∗RuIII{κ3SSS′-tpdt}] (1A) and [Cp∗RuIII{κ3SSN-apdt}] (1B) {Cp∗ = η5-C5Me5; tpdt = S(CH2CH2S−)2; apdt = HN(CH2CH2S−)2} has been initiated by thiolate alkylation or oxidation with iodine. Subsequent electron transfer processes yielded disulfide-bridged dinuclear complexes. The mechanistic pathways of these processes will be discussed.
Keywords
Thiolate , methylation , Cyclopentadienyl ruthenium , Thiyl radical , Disulfide bridge
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377858
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