Title of article :
Germylene complexes of tungsten pentacarbonyls W(CO)5double bond; length as m-dashGeCl2 and W(CO)5double bond; length as m-dashGedouble bond; length as m-dashW(CO)5: Electrochemical synthesis and quantum-chemical computations
Author/Authors :
Yulia G. Budnikova، نويسنده , , Tatyana V. Gryaznova، نويسنده , , Oleg G. Sinyashin، نويسنده , , Sergey A. Katsyuba، نويسنده , , Tatyana P. Gryaznova، نويسنده , , Mikhail P. Egorov، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
Convenient synthetic route to prepare the germylene complexes of tungsten pentacarbonyls, W(CO)5double bond; length as m-dashGeCl2 and W(CO)5double bond; length as m-dashGedouble bond; length as m-dashW(CO)5, electrochemically is developed. Combined quantum-chemical/IR spectroscopic approach is used for identification of the synthesized compounds. Good agreement between theoretical and experimental spectra can be regarded as one of the proofs of their supposed structures.
Keywords :
Dichlorogermylene complex of tungsten pentacarbonyls , Germylenebis(tungsten pentacarbonyl) complex , Electrolysis , Vibrational frequencies , Combined quantum-chemical/IR spectroscopic approach , Cyclic voltammetry
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
