Title of article :
New fulvalenium salts of bis(dicarbollide) cobalt and iron: Synthesis, crystal structure and electrical conductivity
Author/Authors :
Olga N. Kazheva، نويسنده , , Grigorii G. Alexandrov، نويسنده , , Andrey V. Kravchenko، نويسنده , , Vladimir A. Starodub، نويسنده , , Igor B. Sivaev، نويسنده , , Irina A. Lobanova، نويسنده , , Vladimir I. Bregadze، نويسنده , , Lev I. Buravov، نويسنده , , Oleg A. Dyachenko، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
New radical cation salts (BEDT-TTF)2[3,3′-Co(1,2-C2B9H11)2] (1), (BEDT-TTF)2[8-I-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)] (2), (BMDT-TTF)[3,3′-Co(1,2-C2B9H11)2] (3) and (TMTSF)2[3,3′-Fe(1,2-C2B9H11)2] (4) were synthesized and their crystal structures and electrical conductivities were determined. Compound 4 is isostructural to the earlier reported Co analogue. All the radical cation salts synthesized are semiconductors.
Keywords :
crystal structure , Electrical conductivity , Molecular conductors , Bis(methylenedithio)-tetrathiafulvalenium , Cobalt bis(dicarbollide) , Tetramethyltetraselenafulvalenium , Synthesis , Bis(ethylenedithio)-tetrathiafulvalenium , Iron Bis(dicarbollide)
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
