Title of article
Efficient synthesis of ferrocenylenones by Friedel–Crafts acylation with EtAlCl2–Me3Al
Author/Authors
?zdemir Dogan، نويسنده , , Volkan ?enol، نويسنده , , Serhat Zeytinci، نويسنده , , Hasan Koyuncu، نويسنده , , Adnan Bulut، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
5
From page
430
To page
434
Abstract
Efficient synthesis of ferrocenylenones using a Friedel–Crafts acylation reaction is described. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and β-methylcrotonoyl chlorides react with ferrocene in the presence of a Lewis acid (EtAlCl2 or EtAlCl2–Me3Al) to give the corresponding ferrocenylenones (acryloyl, methacryloyl, crotonoyl, cinnamoyl, and methylcrotonoylferrocenes) in good isolated yields. Besides ferrocenylenones, chloroactylferrocene is also synthesised by this method.
Keywords
Ferrocenylenones , Friedel–Crafts acylation , Ethylaluminum dichloride , Lewis acid
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378196
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