Title of article :
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
Author/Authors :
Alexander D. Dilman، نويسنده , , Dmitry E. Arkhipov، نويسنده , , Alexander A. Korlyukov، نويسنده , , Valentine P. Ananikov، نويسنده , , Vitalij M. Danilenko، نويسنده , , Vladimir A. Tartakovsky، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2005
Abstract :
A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations.
Keywords :
Organosilicon chemistry , Tris(pentafluorophenyl)silyl derivatives , Trichlorosilanes , structural studies
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
