Title of article
Cross-coupling of vinyldisilacyclobutane with olefins catalyzed by [RuH(Cl)(CO)(PCy3)2]
Author/Authors
Magdalena Jankowska، نويسنده , , Olga Shuvalova، نويسنده , , Natalia Bespalova، نويسنده , , Mariusz Majchrzak، نويسنده , , Bogdan Marciniec، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
6
From page
4492
To page
4497
Abstract
Cross-coupling of vinyldisilacyclobutane with a variety of olefins in the presence of [RuH(Cl)(CO)(PCy3)2] leads to stereoselective formation of functionalized vinyldisilacyclobutanes. Analogous homo-coupling of vinyldisilacyclobutane leads to the formation of E- and gem-bis(silyl)ethenes. The reaction offers a new route for synthesis of attractive monomers for ring opening polymerization (ROP).
Keywords
Disilacyclobutane derivatives , Ruthenium complex , Vinyldisilacyclobutane , Silylative coupling
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378713
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